Synthesis and Properties of Upper Rim Schiff Base Calix[4]arenes
β Scribed by Tie-Dong Guo; Qi-Yu Zheng; Lian-Ming Yang; Zhi-Tang Huang
- Book ID
- 110257372
- Publisher
- Springer Netherlands
- Year
- 2000
- Tongue
- English
- Weight
- 50 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0923-0750
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## Abstract Four __pβtert__βbutylcalix[4]arene derivatives with different Schiff base groups at the lower rim were efficiently prepared in three steps. __pβtert__βButylcalix[4]arene was firstly __Oβ__peralkylated with __Ο__βhaloalkylphthalimide in the system of NaH/DMF to give calixarene tetraalkyl
Calix[4]arenes containing ferrocene amide at the upper rim and methoxy or ethoxycarbonylmethoxy (ethyl ester) groups at the lower rim (5a, 5b and 5c) have been synthesized. It was found that tetramethoxy 5a and dimethoxy diethyl ester 5c were conformationally labile and existed in both cone and part