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Synthesis and Properties of Tris(trimethylsilyl)aluminum

✍ Scribed by Dr. Lutz Rösch


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
141 KB
Volume
16
Category
Article
ISSN
0044-8249

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ChemInform Abstract: Base-Free Tris(trim
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Base-Free Tris(trimethylsilyl)methyl Derivatives of Lithium, Aluminum, Gallium, and Indium. -Base-free Li-compound (II), prepared by an optimized trivial method, is used to synthesize metallanes (III). It reacts with one equivalent of AlCl3 to give metallate (IV), but reaction with one equivalent o

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Tetrakis(trimethysilyl)phthalocyaninatoruthenium(II) (5) has been synthesized via the biaxially coordinated ((CH 3 ) 3 Si) 4 PcRu(3-Clpy) 2 (2) complex by thermal decomposition of the axial ligands of 2. ((CH 3 ) 3 Si) 4 PcRu (5) was characterized by NMR, IR and UV-vis spectroscopy and elemental ana