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Synthesis and properties of the samarium sulfides

✍ Scribed by M.D. Houston


Book ID
103735576
Publisher
Elsevier Science
Year
1961
Weight
39 KB
Volume
1
Category
Article
ISSN
0365-1789

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Selective synthesis of organic sulfides
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Elemental sulfur can be reduced to the corresponding thiolate anion species (S β€«Χž2‬ and ) se- ## β€«Χž2‬ S 2 lectively by samarium diiodide in the presence and absence of HMPA, respectively. The subsequent alkylation of the thiolate anion species provides a useful synthetic route to dialkyl sulfides