Synthesis and Properties of the First Organosilyl-Gallium Compounds

✍ Scribed by Priv.-Doz. Dr. Lutz Rösch; Dr. Heinrich Neumann

• Publisher: John Wiley and Sons
• Year: 1980
• Tongue: English
• Weight: 248 KB
• Volume: 19
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198000551

✦ Synopsis

Tris(trimethyl)silyl compounds of all GroupIIIB metals are known now that the synthesis of Ga(SiMe~3~)~3~ has been accomplished. The tetrahydrofuran adduct (1) initially obtained can be freed from solvent by sublimation in a high vacuum. Ga(SiMe~3~)~3~ resembles the indium derivative more closely than the (associating) aluminum derivative.
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