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Synthesis and properties of the first crystalline 1,4-ylide, 9-cyano-10-methyl-10-thiaanthracene

✍ Scribed by Mikio Hori; Tadashi Kataoka; Hiroshi Shimizu; Sachio Ohno; Ken'ichi Narita


Book ID
104236947
Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
185 KB
Volume
19
Category
Article
ISSN
0040-4039

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First Synthesis of 9,10-Dimethoxy-2-meth
✍ Dipakranjan Mal; Sutapa Ray 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 243 KB

## Abstract The synthesis of 9,10‐dimethoxy‐2‐methyl‐1,4‐anthraquinone, an unusual quinone, was achieved in five steps from __p__‐benzoquinone. A Kochi–Anderson radical methylation features as the key step in the synthesis. The chemistry of a cyclopropa‐1,4‐anthracenedione is also described. (© Wil