Synthesis and Properties of the Emerging Azacalix[14]arenes
β Scribed by Mounia Touil; Mourad Elhabiri; Mohammed Lachkar; Olivier Siri
- Book ID
- 102830013
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 720 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-193X
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β¦ Synopsis
Abstract
We describe the synthesis and spectrophotometric studies of novel N(H)βazacalix[4]arenes. The unprecedented direct functionalization of the N(H) bridges furnished N(R)βbridged aza[1~4~]calixarene 11 that could complex a neutral guest (CH~2~Cl~2~) or could be further reduced into corresponding tetraamino derivative 12.
π SIMILAR VOLUMES
Since Atwood et al. and Shinkai et al. independently discovered the selective formation of a sparingly soluble C 60 /p-tBu-calix [8]arene complex in toluene in 1994, there has been an increasing interest in supramolecular fullerene chemistry because of its potential applications in chemistry, biol