Synthesis and properties of the complexes of lanthanides with nitronyl nitroxide biradical
✍ Scribed by Zhao Qi-Hua; Li Li-Cun; Liao Dai-Zheng; Jiang Zong-Hui; Yan Shi-Ping; Fang Rui-Bin
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 263 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0256-7660
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## Abstract Two novel adducts of formula Mn(hfaC)~2~(NITPhCLI)~2~ (1) and Mn(hfac)2(IMHPhCl)I~2~(NIT‐PhCl) 0.5H~2~O (2), where hfac = hexafluoroacetylacetonate, NITPhCI = 2–(3‐chlorophenyl)‐4,4,5,5‐tetramethylimidazolyl‐1‐oxyl‐3‐oxide, IMHPhCl = 2‐(3‐chlorophenyl)‐4, 4, 5, 5‐tetramethylimidazolyl‐3
## Abstract The synthesis of biphenyls substituted with nitronyl‐nitroxide organic radicals is described. To investigate the Suzuki‐type cross‐coupling reaction conditions in the presence of the radical, a model compound **1** was prepared. The successful coupling was extended to cyano‐functionaliz