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Synthesis and properties of the complexes of lanthanides with nitronyl nitroxide biradical

✍ Scribed by Zhao Qi-Hua; Li Li-Cun; Liao Dai-Zheng; Jiang Zong-Hui; Yan Shi-Ping; Fang Rui-Bin


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
263 KB
Volume
18
Category
Article
ISSN
0256-7660

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## Abstract Two novel adducts of formula Mn(hfaC)~2~(NITPhCLI)~2~ (1) and Mn(hfac)2(IMHPhCl)I~2~(NIT‐PhCl) 0.5H~2~O (2), where hfac = hexafluoroacetylacetonate, NITPhCI = 2–(3‐chlorophenyl)‐4,4,5,5‐tetramethylimidazolyl‐1‐oxyl‐3‐oxide, IMHPhCl = 2‐(3‐chlorophenyl)‐4, 4, 5, 5‐tetramethylimidazolyl‐3

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## Abstract The synthesis of biphenyls substituted with nitronyl‐nitroxide organic radicals is described. To investigate the Suzuki‐type cross‐coupling reaction conditions in the presence of the radical, a model compound **1** was prepared. The successful coupling was extended to cyano‐functionaliz