Synthesis and Properties of Tetraamminebis(1-methyl-5-aminotetrazole-N3,N4)cobalt(III) Perchlorate
β Scribed by A. Yu. Zhilin; M. A. Ilyushin; I. V. Tselinskii; A. S. Kozlov; N. E. Kuz'mina
- Book ID
- 110416449
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2002
- Tongue
- English
- Weight
- 52 KB
- Volume
- 75
- Category
- Article
- ISSN
- 1070-4272
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Cyanation of bis(4,5-dicyano-l-methyl-2-imidazolyl)arnine(1) using cyanogen chloride gave N,N-bis(4,5-dicyano-l-methyl-2-imidazolyl)cyanamide(3) as a light yellow solid. Compound 3 is themmlly labile and upon heating the N-CN bond is cleaved and the reactive amine intermediate readily reacts with th
## Abstract Two monomeric cobalt(II) complexes, [CoL(N~3~)]ClO~4~ (1) and CoL(N~3~)~2~ (2), where L is tris((3,5βdimethylpyrazolβyl) methyl) amine, were synthesized and their crystal structures were determined by Xβray diffraction technique. Complex 1 is five coordinated with one azide nitrogen ato