✦ LIBER ✦

Synthesis and properties of poly(silylenephenylenevinylene)s

✍ Scribed by Dong Seok Kim; Sang Chul Shim

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 289 KB
Volume: 37
Category: Article
ISSN: 0887-624X
DOI: 10.1002/(sici)1099-0518(19990701)37:13<2263::aid-pola41>3.0.co;2-h

No coin nor oath required. For personal study only.

✦ Synopsis

Polymerization of o-, m-, and p-(dimethylsilyl)

phenylacetylene by chloroplatinic acid-catalyzed hydrosilylation gave the corresponding poly(dimethylsilylenephenylenevinylene)s. The monomer reactivity and polymer structure were very much dependent upon the substituent position. Interesting optical behavior and thermal properties were observed which suggested the polymers to be useful as preceramic materials.

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