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Synthesis and Properties of Polymers Containing Silphenylene Moiety via Catalytic Cross-Dehydrocoupling Polymerization of 1,4-Bis(dimethylsilyl)benzene

✍ Scribed by Li, Yuning; Kawakami, Yusuke


Book ID
126210725
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
254 KB
Volume
32
Category
Article
ISSN
0024-9297

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## Abstract Polymerizations of 2‐methylpropene (MP) initiated by the system 1,4‐bis(1‐azido‐1‐methylethyl)benzene (DAMEB)/BCl~3~ in the presence of DMSO were carried out by “all monomer in” (AMI) technique at −70°C in CH~2~Cl~2~ solution. FT‐IR, ^1^H NMR and SEC analyses of polymers (PMP) showed th