2,2,ะ3,3ะ-Biphenyltetracarboxylic dianhydride (2,2,ะ3,3ะ-BPDA) was prepared by a coupling reaction of dimethyl 3-iodophthalate. The X-ray single-crystal structure determination showed that this dianhydride had a bent and noncopolanar structure, presenting a striking contrast to its isomer, 3,3,ะ4,4ะ
Synthesis and properties of polyimides derived from isomeric biphenyltetracarboxylic dianhydrides
โ Scribed by I. Rozhanskii; K. Okuyama; K. Goto
- Book ID
- 108366097
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 246 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0032-3861
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๐ SIMILAR VOLUMES
Four series of aromatic polyimides (PIs V-VIII) composed of biphenyltetracarboxylic dianhydrides (BPDAs) and aromatic diamines bearing alkylene spacers were prepared by two methods. Most polymers could be readily prepared in a one-step method for the combination of a-BPDA with โฃ,-bis(3-aminophenoxy)
Four new diimide-dicarboxylic acids (I-IV) were prepared by condensation of s-or a-BPDA with para-or meta-aminobenzoic acid. A series of aromatic poly(amideimide)s containing these diimide-dicarboxylic units was prepared by three methods: (1) acid chloride method, (2) triphenylphosphite method, and