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Synthesis and properties of polyacetylenes with electron donor substituents

โœ Scribed by S.M Fomin; G.N Gerasimov; A.I Stash; V.M Vozzhennikov; I.V Bulgarovskaya; E.N Teleshov

Book ID
116050105
Publisher
Elsevier Science
Year
1991
Weight
499 KB
Volume
33
Category
Article
ISSN
0032-3950

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Synthesis and properties of polyacetylen
Synthesis and properties of polyacetylenes with adamantyl groups
โœ Masahiro Teraguchi; Toshio Masuda ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 194 KB ๐Ÿ‘ 2 views

Three disubstituted acetylenes with an adamantyl group-1-(p-adamantylphenyl)-2-chloroacetylene (ClpAdPA), 1-(p-adamantylphenyl)-1-propyne (pAdPP), and 1-(p-adamantylphenyl)-2-phenylacetylene (pAdDPA)-polymerized in good yields in the presence of MoCl 5 -or TaCl 5 -based catalysts. The highest weight