Synthesis and Properties of Photo-responsive Tetrathiafulvalene derivatives
β Scribed by K. Sako; M. Kusakabe; H. Fujino; S.X. Feng; H. Takemura; T. Shinmyozu; H. Tatemitsu
- Book ID
- 117539832
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 333 KB
- Volume
- 137
- Category
- Article
- ISSN
- 0379-6779
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## Abstract Two new unsymmetrical tetrathiafulvalene (TTF) derivatives, 2,3βbis(cyanoethylthio)β6,7β(methylβethylenedithio)tetrathiafulvalene (**6a**) and 2,3βbis(cyanoethylthio)β6,7β(cyclopentodithio)tetrathiafulvalene (**6b**), have been prepared and characterized by NMR, MS, IR and Elemental ana
Palladium(II)-or copper(II)-catalyzed homo-coupling reaction of either trimethylstannyltetrathiafulvalene or tetrathiafulvalenylzinc chloride produces symmetrical bitetrathiafulvalenes (bi-TTFs) in good yields, whereas palladium(0)catalyzed cross-coupling reaction of tetrathiafulvalenylzinc chloride