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Synthesis and properties of optically active 6,6′-didodecyl-1,1′-binaphthyl-phthalocyanine linked through crown ether units

✍ Scribed by Hongwei Liu; Yaohu Liu; Minghua Liu; Chuanfu Chen; Fu Xi


Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
166 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis


A novel optically active 6,6%-didodecyl-1,1%-binaphthyl-metallophthalocyanine linked through crown ether units ((S)-Pc) has been synthesized. A stable monolayer of (S)-Pc that is able to bind metal ions can be formed at the air-water interface. Nonlinear absorption and optical limiting behavior of (S)-Pc have also been observed.


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A series of racemic and enantiomerically pure 6,6'-dinitro-l,l'-binaphthyl-2,2'-diethers 1 have been synthesized by the nitration of the corresponding cyclic ethers and both the reactivity of nitration and the (chir)optical properties proved to be very sensitive for the chain length of the ether bri