Synthesis and Properties of Onium Salts of Isocyanuric Acid. Crystal Structure of Tetraphenylphosphonium Isocyanurate
β Scribed by A. M. Flakina; A. N. Chekhlov; P. P. Kushch; R. N. Lyubovskaya
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 97 KB
- Volume
- 75
- Category
- Article
- ISSN
- 1070-3632
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## Abstract The reaction between isocyanuric acid and ethylene carbonate results in the formation of polyetherols. The kinetic and mechanistic studies revealed that the initial step of the reaction is zero order related to ethylene carbonate. The rateβlimiting step is the decomposition of an interm
## Abstract The kinetics and mechanism of the reaction between isocyanuric acid and ethylene carbonate was studied. The multistep reaction in the presence of potassium carbonate as catalyst leads to polyetherols. The imide and hydroxyl groups of intermediates react with ethylene carbonate by slight