In the preceding paper, we reported the syntheses of tetrasubstituted didehydro [l&]annulenes by dehydroxylative aromatieation of l&-membered cyclic glycols which could be prepared by cyclic dimerieation of l,
โฆ LIBER โฆ
Synthesis and properties of naphtho[2,1-c]-9,12,18-tri-t-butyl-1,10-didehydroc[18]annulene
โ Scribed by Masakazu Morigaki; Masahiko Iyoda; Masazumi Nakagawa
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 213 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
previous papers, we reported the synthesis and diatropicity of 1,8-didehydro[14]annulenes annelated with naphthalene (1,2) or bensene (3). It seemed of considerable interest to prepare l, lO-didehydro[18]annulene fused with bensenoid system to compare the ring current in the 18n-electron system with that
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The diacetylene and hexapentaene units in the aromatic tetrasubstitutedtetradehydro-[18]annulenes (Ia, Ib and I,) have been proved to be identical in