Synthesis and Properties of Isoxazolo[60]fullerene−Donor Dyads †
✍ Scribed by Langa, Fernando; de la Cruz, Pilar; Espíldora, Eva; González-Cortés, Araceli; de la Hoz, Antonio; López-Arza, Vicente
- Book ID
- 120583465
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 272 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0022-3263
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Starting from quercetin, a natural flavonol with high antioxidant activity, three novel [60]fullerene-flavone derivatives were synthesized via cyclopropanation of C 60 .
Two series of [60]fullerene-linked oligo(2,3-thienylene-ethynylene)s and oligo(2,5-thienylene-ethynylene)s have been synthesized to elucidate their photophysical characteristics. Their fluorescence spectra in toluene reveals distinct photoinduced intramolecular interactions between the oligomers and
New dumb-bell-type fullerene adducts 2, 4, and 8a-b could used to link the archimedic polyhedron fullerene with the platonic element cubane. When a bulky spacer between the be synthesized via bifunctional nitrile oxides. The [60]fullerene derivative 16 of this type was synthesized by fullerene units