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Synthesis and Properties of Iron(II) and Manganese(II) Complexes Derived from a Topologically Constrained Pentadentate Ligand

✍ Scribed by Collinson, Simon; Alcock, Nathaniel W.; Raghunathan, Ahasuya; Kahol, Pawan K.; Busch, Daryle H.


Book ID
120637600
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
143 KB
Volume
39
Category
Article
ISSN
0020-1669

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Manganese(II) and iron(II) derivatives o
✍ Sushil K. Gupta; Anoop Kelkar πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 223 KB

## Abstract Treatment of anhydrous MCl~2~ (M = Mn, Fe) with (Ph~2~PMe~2~Si)~3~CH in toluene at elevated temperature resulted in the isolation of colorless (MnCl~2~{(Ph~2~PMe~2~Si)~3~CH}) (1) and light yellow (FeCl~2~{(Ph~2~PMe~2~Si)~3~CH}) (2) in high yield. These paramagnetic complexes have been c