The five-step synthesis of the first transition metal complex CH 2 PPh 2 (9), silylated cyclopentadiene (CH 3 ) 3 SiC 5 (CH 3 ) 4 -CH 2 CH 2 PPh 2 (10) and cyclopentadiene HC 5 (CH 3 ) 4 CH 2 -with the C 5 (CH 3 ) 4 CH 2 CH 2 PPh 2 ligand [η 5 :η 1 -C 5 -(CH 3 ) 4 CH 2 CH 2 PPh 2 ]ZrCl 3 •THF (11),
✦ LIBER ✦
Synthesis and Properties of Group 13 Element Compounds (Al, Ga, In) with the Polydentate 1-[2-(Dimethylamino)ethyl]-2,3,4,5-tetramethylcyclopentadienyl Ligand. X-ray Crystal Structures of (C 5 Me 4 CH 2 CH 2 NMe 2 )MX 2 (MX 2 = AlMe 2 , AlCl 2 , InCl 2 ) 1
✍ Scribed by Jutzi, Peter; Dahlhaus, Jürgen; Neumann, Beate; Stammler, Hans-Georg
- Book ID
- 126014648
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 261 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0276-7333
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