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Synthesis and properties of cyclic ethylene-bridged 3,6-fluorene dimer and its linear analogues

✍ Scribed by Yabin Song; Wei Xu; Daoben Zhu


Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
694 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis


Three oligomers of ethylene-bridged 3,6-fluorene were synthesized starting from phenanthrenequinone.

McMurry reaction was applied to synthesize the cyclic compound. Horner-Emmons reaction was used to synthesize the linear compounds with all-trans configuration. The crystal structure of the cyclic compound was described. The optical and electronic properties of these compounds were fully characterized and compared.


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