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Synthesis and properties of conductive radical cation salts of MDT-TSF (methylenedithiotetraselenafulvalene)

โœ Scribed by K Takimiya; Y Kataoka; M Kodani; Y Aso; T Otsubo

Book ID
117539124
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
129 KB
Volume
133-134
Category
Article
ISSN
0379-6779

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Novel Conductive Radical Cation Salts Based on Methylenediselenotetraselenafulvalene (MDSe-TSF): A Sign of Superconductivity in ฮบ-(MDSe-TSF)2Br Below 4 K
โœ Mie Kodani; Ayumi Takamori; Kazuo Takimiya; Yoshio Aso; Tetsuo Otsubo ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 301 KB

Seven conductive radical cation salts based on MDSe-TSF (methylenediselenotetraselenafulvalene) have been synthesized by electrocrystallization in the presence of Cl ร€ , Br ร€ , I ร€ 3 ; I 2 Br ร€ , PF ร€ 6 ; ClO ร€ 4 ; and CuรฐNCSรž ร€ 2 counter anions. The crystal appearances of these salts fairly depend