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Synthesis and properties of axially disubstituted monomeric and oligomeric phthalocyaninato ruthenium(II) compounds

✍ Scribed by Michael Hanack; Sabine Kamenzin; Christiane Kamenzin; L.R. Subramanian


Book ID
117543441
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
223 KB
Volume
110
Category
Article
ISSN
0379-6779

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The present Letter deals with three ruthenium(I1) porphyrins: RuTBP(C0) (EtOH), RuTBP(pyzft and [RuTBP(pyz)],, where TBP=tetrakis( 3,5~i-tee-butyl-~hydroxyph~nyl) po~h~in, EtOH=ethanol and pyz=pyrazine. Their photophysical properties are studied by steady-state and time-resolved absorption and emis

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Bridged 2,3-naphthalocyaninatoruthenium oligomers { [MacRu(L)], } were synthesized and characterized using solid-state methods. For comparison, soluble t-butyl substituted phthalocyaninatoruthenium oligomers were prepared and their chain length examined by H NMR spectroscopy. The powder conductiviti