The titled quinone compound has been synthesized, and life X-ray ca'yslallographie a~alysis of this compound revealed that it has anti-anti-configuration for stereochemical relationship between two methylene and sulfur bridges. Its 1H and 13C NMR spectra in D2SO 4 inticate that the cationic species
β¦ LIBER β¦
Synthesis and properties of anti-6,15-epithia-8,13-methano-benzo[d][14]annulene-7,14-dione and its dicationic and dianionic species
β Scribed by Sigeyasu Kuroda; Mitsunori Oda; Shin-ya Kuramoto; Yoshihiro Mizukami; Ichiro Shimao
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 284 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The molecular structures of the title compounds 3 and 5 were investigated by NMR and Xβray structural methods. The NMR results suggest two equivalent halves for both molecules. The Xβray study shows an approximate mirror plane for 3 and an approximate twofold axis for a significant port