✦ LIBER ✦

Synthesis and Properties of Allyl Hydroperoxide

✍ Scribed by Dr. H. E. Seyfarth; J. Henkel; Prof. Dr. A. Rieche

Publisher: John Wiley and Sons
Year: 1965
Tongue: English
Weight: 222 KB
Volume: 4
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.196510742

No coin nor oath required. For personal study only.

✦ Synopsis

With sodium borohydride in tetrahydrofuran/ethanol (5 : 1).

the product ( I ) gives a 75 yield of a compound, m.p. 233 "C, that is identical with the recently prepared 2-(diphenylmethyl)imidaz0le[~1. When product ( I ) is boiled for 2 h in tetrahydrofuran/water (2: I ) it affords 2-(hydroxy-dipheny1methyl)imidazole in 72 % yield. Addition of the calculated amount of ethereal hydrogen chloride to a solution of product ( I ) in tetrahydrofuran regenerates the starting material (2) almost quantitatively.

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