Synthesis and properties of a symmetrical macroheterocyclic compound containing 1,3,4-thiadiazole residues
✍ Scribed by V. F. Borodkin; N. A. Kolesnikov
- Book ID
- 112327417
- Publisher
- Springer US
- Year
- 1971
- Tongue
- English
- Weight
- 168 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0009-3122
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## Abstract magnified image The syntheses of new macrocyclic compounds are described. The 2,5‐bis(hydroxyphenyl)‐1,3,4‐thiadiazole reacts with allyl bromide to give the corresponding allyloxy derivative. The allyl is used to functionalize the ortho position by means of a Claisen rearrangement unde
## Abstract New macrocyclic polyether compounds containing a 2,5‐bis(2‐hydroxyphenyl)‐1,3,4‐thiadiazole moiety have been prepared by a nucleophilic substitution reaction involving ethylene or polyethylene glycol ditosylate and a bisphenol, the 2,5‐bis(2‐hydroxyphenyl)‐1,3,4‐thiadiazole, with solid