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Synthesis and properties of 5-substituted 2-thiobarbituric acid dyes

✍ Scribed by Shuzo Akiyama; Kenichiro Nakashima; Shin'ichi Nakatsuji; Mari Suzuki; Chiemi Umekawa


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
227 KB
Volume
8
Category
Article
ISSN
0143-7208

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Synthesis of 5-(functionalized acyl)-1,3
✍ Hanafi H. Zoorob; Mohamed A. Ismail; Lucjan Strekowski πŸ“‚ Article πŸ“… 2001 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 53 KB

## Abstract A sodium derivative of 1,3‐dimefhylbarbituric acid or 1,3‐diethyl‐2‐thiobarbituric acid undergoes an efficient monoacylation at C5 by the reaction with ω‐chloroalkanoyl chloride or diacid dichloride in the presence of pyridine in tetrahydrofuran. A nucleophilic displacement of the chlor