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Synthesis and Proinflammatory Properties of Muramyl Tripeptides Containing Lysine and Diaminopimelic Acid Moieties

✍ Scribed by Abhijit Roychowdhury; Margreet A. Wolfert; Geert-Jan Boons

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
259 KB
Volume
6
Category
Article
ISSN
1439-4227

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Chain-extension of L-glutamate aldehyde 3 by means of the Wittig-Horner reaction furnished the desired C 7 dicarboxylic acid derivative, which in turn, after C-C double bond hydrogenation and protecting group manipulation, afforded the 2,6-diaminopimelic acid derivatives (S,R)-9 and (S,S)-9, both wi