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Synthesis and Preparative Resolution of the trans-Cyclohexane Analogues of Phenylalanine

✍ Scribed by Carlos Cativiela; Pilar López; Marta Lasa

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
192 KB
Volume
2004
Category
Article
ISSN
1434-193X

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Synthesis of fluorinated α-amino ketones
Synthesis of fluorinated α-amino ketones, III. Preparation of fluorinated ketone analogues of phenylalanine, lysine, andp-(Guanidino)phenylalanine
✍ Kolb, Michael ;Neises, Bernhard ;Gerhart, Fritz 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 688 KB

## Abstract The synthesis of α‐amino mono‐, di‐, and trifluoromethyl and difluoromethylene ketones and their derivatives is described. A one‐pot sequence related to the Dakin‐West reaction starts from amino acids and gives the corresponding fluorinated ketone analogues in good yields. The compounds