𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and preliminary evaluation of ordered aliphatic poly(benzoxazole amides),

✍ Scribed by De Winter, Walter ;Stein, Ralph ;Uwents, Henri ;Masquelier, Camille


Book ID
104535402
Publisher
Wiley (John Wiley & Sons)
Year
1970
Tongue
English
Weight
522 KB
Volume
8
Category
Article
ISSN
0449-296X

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✦ Synopsis


Abstract

Slightly modified conventional techniques were successfully applied to prepare aliphatic benzoxazolediamines and the corresponding high molecular weight polyamides, which could be spun into excellent fibers. Compared to regular aliphatic polyamides, these products showed higher transition temperatures, improved thermal and light stability, and increased affinity for acid dyes. In additionβ€”quite unexpectedlyβ€”these fibers were highly crystalline and oriented after drawing at elevated temperatures.


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## Abstract Four aromatic diamines containing aliphatic spacers and __Meta__ and __para__ oriented oxyphenylene rings, and their corresponding hydrochlorides, were combined with isophthaloyl chloride (IPC) and terephthaloyl chloride (TPC) to give high molecular weight polyamides by interfacial and