Synthesis and preliminary evaluation of ordered aliphatic poly(benzoxazole amides),
β Scribed by De Winter, Walter ;Stein, Ralph ;Uwents, Henri ;Masquelier, Camille
- Book ID
- 104535402
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1970
- Tongue
- English
- Weight
- 522 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0449-296X
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β¦ Synopsis
Abstract
Slightly modified conventional techniques were successfully applied to prepare aliphatic benzoxazolediamines and the corresponding high molecular weight polyamides, which could be spun into excellent fibers. Compared to regular aliphatic polyamides, these products showed higher transition temperatures, improved thermal and light stability, and increased affinity for acid dyes. In additionβquite unexpectedlyβthese fibers were highly crystalline and oriented after drawing at elevated temperatures.
π SIMILAR VOLUMES
## Abstract Four aromatic diamines containing aliphatic spacers and __Meta__ and __para__ oriented oxyphenylene rings, and their corresponding hydrochlorides, were combined with isophthaloyl chloride (IPC) and terephthaloyl chloride (TPC) to give high molecular weight polyamides by interfacial and