✦ LIBER ✦

Synthesis and polymerization of unsaturated monomers with OH groups in their structure: 2-(hydroxyethyleneoxyterephthaloyloxy) ethyl acrylate

✍ Scribed by J. Guzmán; E. Riande

Book ID: 104769571
Publisher: Springer
Year: 1995
Tongue: English
Weight: 229 KB
Volume: 34
Category: Article
ISSN: 0170-0839
DOI: 10.1007/bf00423345

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✦ Synopsis

The synthesis and polymerization of new unsaturated monomers derived from acrylic acid and an aliphatic-aromatic glycol is reported. Values of kv/kt la were obtained for the monoacrylate monomer and compared with those found for other acrylic monomers.

The thermal properties of the starting glycol (Bis[2-hydroxyethyl]terephthalate), monomers (monoacrylate and diacrylate) and linear polymer were determined by calorimetric techniques. The results show the influence of intermolecular interactions (hydrogen bondmgs) on these properties.

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