Synthesis and Polymerization of Novel Vinyl Monomers having Intramolecular Urethane Bond and Glycerin Group
β Scribed by Kang, Eui-Chul; Ogura, Atsuhiko; Iwata, Takashi; Kataoka, Shingo; Maruhashi, Yutaka
- Book ID
- 111776809
- Publisher
- Nature Publishing Group
- Year
- 2006
- Tongue
- English
- Weight
- 105 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0032-3896
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π SIMILAR VOLUMES
The radical polymerization of N-acryloyl-N-(p-tolylsulfonyl)urea ( 2), prepared easily by the reaction of p-toluenesulfonyl isocyanate with acrylamide, was carried out in DMF, DMSO, or NMP at 60ΠC by use of AIBN as an initiator to give a polymer 3 in a good yield. Copolymerization parameters of 2 we
New hybrid vinyl monomers with both cationic-and radical-polymerizable vinyl groups were synthesized by the reaction of bis[ l-(chloromethyl)-2-(vinyloxy)ethyl]terephthalate (3) with unsaturated carboxylic acids using 1,8-diazabicyclo[5.4.0] -undecene-7 (DBU) as a base. The reaction of 3 with methac