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Synthesis and Physical Properties of Sterically Congested Cycloalkenes, 1,2-Di- tert -butyl-3,3,5,5-tetramethylcyclopentene and 1,2-Di- tert -butyl-3,3,6,6-tetramethylcyclohexene

✍ Scribed by Ishii, Akihiko; Tsuchiya, Chie; Shimada, Takahiro; Furusawa, Ken; Omata, Takenori; Nakayama, Juzo

Book ID
126150213
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
239 KB
Volume
65
Category
Article
ISSN
0022-3263

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The Reactions of 3,6-Di-tert-butyl-1,2-benzoquinone and 3,6-Ditert-butylcatechol with tert-Butyl Hydroperoxide. -The reaction of the title quinone (I) as well as its corresponding catechol with tert-butyl hydroperoxide in aprotic solvents results in ring oxidation accompanied by ring expansion furn