Synthesis and photopolymerization of 4-(1-propenyl)oxybutyl acrylate
β Scribed by S. J. Li; Y. He; J. Nie
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 375 KB
- Volume
- 110
- Category
- Article
- ISSN
- 0021-8995
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Several 1-butenyl and 1-pentenyl ether monomers were prepared by the ruthenium catalyzed multistage double bond isomerization of the corresponding 3-butenyl and 4-pentenyl ethers and characterized. Employing tris(triphenylphosphine)ruthenium(II) dichloride as a catalyst, the isomerization of octyl 4
1-Butenyl glycidyl ether was prepared in high yield by the rutheniumcatalyzed isomerization of crotyl glycidyl ether. This ambifunctional monomer underwent facile photoinitiated cationic polymerization using diaryliodonium salts as photoinitiators. The progress of the polymerizations was followed us