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Synthesis and Photophysics of a Neutral Organic Mixed-Valence Compound

✍ Scribed by Alexander Heckmann; Christoph Lambert; Mark Goebel; Rüdiger Wortmann


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
277 KB
Volume
43
Category
Article
ISSN
0044-8249

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The deprotonation of the 4H-imidazoles 1 by lithium hydride Alkylation, as well as acylation, of 2 leads to the exocyclic substituted derivatives 3 and 5. The NMR spectra of 3 and 5 yields the lithiated derivatives 2 which contain a stable delocalized anion. Surprisingly, the X-ray crystal structure