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Synthesis and Photophysical Properties of Alkoxysilyl Derivatives of Dibenzoylmethanatoboron Difluoride

✍ Scribed by Kononevich, Yuriy N.; Meshkov, Ivan B.; Voronina, Natalia V.; Surin, Nikolay M.; Sazhnikov, Viacheslav A.; Safonov, Andrei A.; Bagaturyants, Alexander A.; Alfimov, Mikhail V.; Muzafarov, Aziz M.

Book ID
120315090
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
928 KB
Volume
24
Category
Article
ISSN
1042-7163

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Dibenzomethanatoboron difluoride (DBMBF 2 ) interacted with alkylbenzenes from its singlet excited state to form exciplexes ranging from weak polarity up to contact radical ion pairs (CRIP); this exciplex series shows the characteristics in the Marcus ΒͺnormalΒΊ region. In cyclohexane these exciplexes