A novel class of crown ether-bearing [60]fulleropyrrolidines containing a benzothiazolium styryl dye has been synthesized. The compounds have been characterized by FT-IR, NMR and mass spectra. The UV-vis absorption spectra of the compounds have also been studied.
Synthesis and photophysical characterization of a new crown ether-bearing [70]fulleropyrrolidine derivative
β Scribed by Zhongxin Ge; Yuliang Li; Zhiqiang Shi; Fenflian Bai; Daoben Zhu
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 158 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0022-3697
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β¦ Synopsis
A novel class of crown ether-bearing [70]fulleropyrrolidines containing a benzothiazolium styryl dye has been synthesized. The compounds have been characterized by FT-IR, NMR and mass spectra. The UV-Vis absorption and fluorescence spectra of the compounds have also been studied, which show the absorption and emission peaks of the compounds can be hypsochromically shifted by alkaline and alkaline-earth metal ions complexation.
π SIMILAR VOLUMES
Photochromism / Photoresponsive crown ether Photosensitive crown ether 1 composed of 1,8a-dihydroazulene as a photodynamic unit and a benzo[l5]crown-5 ether subgroup has been synthesized from C-Tsubstituted cycloheptatriene 8, which has been obtained by nucleophilic addition of 4-acetylbenzo[l5]crow
A b#tract: New ionophores having clffefeat size of crown ethet~ wee prepared from a rigid ,..alixanme analog in 72-98% yields. They dfic~ently extracted the alkali metal ions. Their ion selectivity was apparently changed by the size of crown ether.