Synthesis and photoluminescence properties of self-assembled Eu-doped ZnO hollow microspheres
β Scribed by Xu, Jin ;Wang, Nating ;Wang, Weiqiang
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 515 KB
- Volume
- 208
- Category
- Article
- ISSN
- 0031-8965
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β¦ Synopsis
Abstract
ZnO hollow microspheres with a shell wall consisting of crystalline ZnO nanosheets were synthesized by using Zn~5~(CO~3~)~2~(OH)~6~ microspheres as spherical templates. Zn~5~(CO~3~)~2~(OH)~6~ microspheres were first fabricated by a solvothermal procedure in an ethylene glycol (EG)βwater solution. ZnO microspheres with a hexagonal structure were identified by means of Xβray diffraction (XRD) and selectedβarea electron diffraction (SAED). On the basis of the results, a possible selfβassembly growth mechanism was proposed. It reveals that the EG played an important role in determining the hollow morphologies of Zn~5~(CO~3~)~2~(OH)~6~ structures. In addition, photoluminescence (PL) investigation of ZnO:Eu^3+^ suggested that a direct energy transfer occurred, which was ascribed to the energy transfer from ZnO host to Eu^3+^ ions.
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