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Synthesis and particle size effect on the phase transformation of nanocrystalline TiO2

✍ Scribed by Chung-Sik Kim; Il-Min Kwon; Byung Kee Moon; Jung Hyun Jeong; Byung-Chun Choi; Jung Hwan Kim; Haeyoung Choi; Soung Soo Yi; Dae-Hwang Yoo; Kyong-Soo Hong; Jong-Ho Park; Ho Sueb Lee

Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
609 KB
Volume
27
Category
Article
ISSN
0928-4931

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With the aid of ab initio calculations, we compare the phase behavior upon lithiation of rutile particles of different sizes and morphologies. A rationale for the differences in their structural behavior is provided by combining concepts from Crystal Field Theory and semi-empirical concepts, such as