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Synthesis and Oxidation of Iron(II) Ferrocenylacetylide Diphosphine Complexes. A Novel Type of Mixed-Valence Complex

✍ Scribed by Sato, Masaru; Hayashi, Yukiko; Kumakura, Shigekazu; Shimizu, Natsuko; Katada, Motomi; Kawata, Satoshi

Book ID
126052601
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
308 KB
Volume
15
Category
Article
ISSN
0276-7333

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The Bl,CI,C2 plane forms an angle of 85" with the CI,B2,C14 plane. The duryl rings are twisted by 49 and 88" with respect to the BI,Cl,C2 and C2,B2,C1 planes. The C1C2 bond of 137 pm in the three-membered ring is considerably longer than the CC double bonds in cyclopropenes (130 pm ["]) but the same