Synthesis and Oxidation of Chiral 2-Thiazolines (4,5-Dihydro-1,3thiazoles). -Eight new chiral thiazolines (IV) and (X) are prepared by treatment of oxazolines (III) or alcohols (IX) with P2S5. These thiazolines are oxidized using various agents. -(AITKEN, R. A.; ARMSTRONG, D. P.;
Synthesis and oxidation of chiral 2-thiazolines (4,5-dihydro-1,3-thiazoles)
✍ Scribed by Aitken, R. Alan; Armstrong, David P.; Galt, Ronald H. B.; Mesher, Shaun T. E.
- Book ID
- 111949860
- Publisher
- Royal Society of Chemistry
- Year
- 1997
- Weight
- 537 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1472-7781
- DOI
- 10.1039/a605539g
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Stable benzene‐fused polysulfide compounds, 3,4‐dihydro‐1,2,5‐benzotrithiepins (1a‐c), have been prepared, and the structure of 1a has been determined by X‐ray crystallographic analysis. While the electrophilic oxidation of compounds 1 with m‐chloroperbenzoic acid gave the corresponding
## Abstract magnified image A new method for the synthesis of substituted 5‐(2‐hydroxyethyl)‐2‐phenylimino‐1,3‐thiazolidin‐4‐ones and 5‐(2‐hydroxyethyl)‐2‐phenylamino‐4,5‐dihydro‐1,3‐thiazol‐4‐ones is described, starting from phenylthioureas and 3‐bromotetrahydrofuran‐2‐one. The reaction proceeds