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Synthesis and oxidation chemistry of dimanganese(II,II) complex of biological relevance

โœ Scribed by Sadako Imai; Masahisa Osawa; Yoshihiko Moro-oka; Nobumasa Kitajima


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
66 KB
Volume
51
Category
Article
ISSN
0162-0134

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## Abstract A dinuclear manganese complex {[Mn~2~^II,III^L(ฮผโ€OAc)~2~]ClO~4~} has been synthesised, where L is the dianion of 2โ€{[bis(pyridโ€2โ€ylmethyl)amino]methyl}โ€6โ€{[(3,5โ€diโ€__tert__โ€butylโ€2โ€hydroxybenzyl)(pyridโ€2โ€ylmethyl)amino]methyl}โ€4โ€methylphenol, an unsymmetric binucleating ligand with two