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Synthesis and multinuclear NMR characterization of iminophosphoranyl phosphines and silanes

✍ Scribed by Stéphanie Goumri; Francis Lacassin; Antoine Baceiredo; Guy Bertrand

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
290 KB
Volume
7
Category
Article
ISSN
1042-7163

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✦ Synopsis

Tris (iminotripheny1phosphoranyl)phosphonium chloride 2 , tris(iminorriphenylphosphorany1)phosphine 3, bis(iminotriphenylphosphorany1)dichlorosilane

4,

tris(iminotriphen.ylphosphorany1)-chlorosilane 5 and -hydrogenosilane 6 have been prepared by reacting the iminotriphenylphosphorane 1 with trichbrophosphine or the corresponding chlorosilanes. A multinuclear NMR study of these compounds is presented.

📜 SIMILAR VOLUMES

The characterization of NMR shielding in
The characterization of NMR shielding in monocyclic phosphines
✍ D. B. Chesnut; L. D. Quin; S. B. Wild 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 178 KB

The phenyl-substituted saturated monocyclic phosphines, PhP(CH 2 ) n , n ‫ס‬ 2-5, show an interesting variation in their phosphorus NMR shieldings. The shielding does not vary uniformly with ring size, but rather the smallest ring (n ‫ס‬ 2) has the highest shielding while the next smallest (n ‫ס‬ 3)