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Synthesis and molecular structure of nickel-antimony alkoxide, Ni5Sb3O2(OEt)15(HOEt)4

✍ Scribed by Bemm, U.; Norrestam, R.; Nygren, M.; Westin, G.


Book ID
126438773
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
544 KB
Volume
31
Category
Article
ISSN
0020-1669

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A new manganese-antimony oxoethoxide with the formula Mn 7 Sb 4 O 4 (OEt) 18 (HOEt) 2 has been prepared and characterized by single-crystal X-ray diffraction and FT-IR techniques. The structure of the compound has the noncentrosymmetric tetragonal space group symmetry P4 2 (No. 77) with unit-cell pa

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A new bimetallic oxoalkoxide, with composition \(\mathrm{Sr}_{2} \mathrm{Sb}_{4} \mathrm{O}(\mathrm{OEt})_{14}\), has been synthesized by reacting \(\mathrm{Sr}(\mathrm{OEt})_{2}\) with an excess of \(\mathrm{Sb}(\mathrm{OEt})_{3}\) in toluene-ethanol under a dry nitrogen atmosphere. Colorless trans