Synthesis and Molecular Structure of [{[CH3C(CH2PPh2)3]IrP3}3Cu5Br4]CuBr2: A 21-Atom Mixed Iridium/Copper/Phosphorus/Bromine Cluster
β Scribed by Mr. Franco Cecconi; Dr. Carlo A. Ghilardi; Dr. Stefano Midollini; Dr. Annabella Orlandini
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 177 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The five-step synthesis of the first transition metal complex CH 2 PPh 2 (9), silylated cyclopentadiene (CH 3 ) 3 SiC 5 (CH 3 ) 4 -CH 2 CH 2 PPh 2 (10) and cyclopentadiene HC 5 (CH 3 ) 4 CH 2 -with the C 5 (CH 3 ) 4 CH 2 CH 2 PPh 2 ligand [Ξ· 5 :Ξ· 1 -C 5 -(CH 3 ) 4 CH 2 CH 2 PPh 2 ]ZrCl 3 β’THF (11),
## Abstract The first argentate salt of carborane anion, [{(CH~3~CN)~4~Ag~3~}{Ag(CB~11~I~5~Br~6~)~2~}]~__n__~, was prepared from K~2~[CB~11~I~5~Br~6~] and AgNO~3~ followed by recrystallization from acetonitrile. Singleβcrystal Xβray analyses indicate that the CB~11~I~5~Br~6~^2β^ dianion has a signi