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Synthesis and molecular structure of bis(2,6-dimethylpyridine)bis-(trifluoroacetate)Cr(II) with an unusual square planar environment of the chromium atom

✍ Scribed by I.L. Eremenko; A.A. Pasynskii; V.T. Kalinnikov; G.G. Aleksandrov; Yu.T. Struchkov


Book ID
104138049
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
191 KB
Volume
54
Category
Article
ISSN
0020-1693

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Reaction between 2,3,5,6-tetrakis(a-pyridyl)pyrazine (TPP) and the dimer , in which TPP behaves as a bis(bidentate) ligand between the two Pt atoms of the cation. Insertion of SnCl 2 into the Pt-Cl bonds of this compound led to an unusual rearranged product, (2), with a rare example of a pentacoor