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Synthesis and modelling of novel rigid rods derived from a simple pentacyclic bis-norbornene [1]

✍ Scribed by Davor Margetic; Martin R. Johnston; Edward R.T. Tiekink; Ronald N. Warrener

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
230 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

New rigid rods with 4~, 6c, 10~, 12~, and 16~ bond separations have been prepared from the pentacyclic diene 3 using ACE (alkene plus cyclobutene epoxide) and s-tetrazine coupling techniques and their shapes evaluated using AM1 calculations. The X-ray structure of the 6~-rod 5 is reported.

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