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Synthesis and Micellar Characterization of Novel Amphiphilic A−B−A Triblock Copolymers of N-(2-Hydroxypropyl)methacrylamide or N-Vinyl-2-pyrrolidone with Poly(ε-caprolactone)

✍ Scribed by Lele, B. S.; Leroux, J.-C.


Book ID
115506204
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
147 KB
Volume
35
Category
Article
ISSN
0024-9297

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## Abstract The kinetics and controllability of the Ti[OCH~2~CCl~3~]~4~‐initiated atom transfer radical polymerization (ATRP) of __n__‐butyl acrylate were investigated. Then, with Ti[OCH~2~CCl~3~]~4~ as the initiator, poly(ϵ‐caprolactone)‐__block__‐poly(__n__‐butyl acrylate) (PCL‐__b__‐PBA) copolym