Synthesis and mass spectra of derivatives of (η5-cyclopentadienyl)(η4-cyclopentadiene)cobalt
✍ Scribed by G.A. Razuvaev; V.P. Mar'in; Yu.A. Andrianov; L.I. Vyshinskaya; O.N. Druzhkov
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 602 KB
- Volume
- 346
- Category
- Article
- ISSN
- 0022-328X
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Electron impact mass spectra of substituted norbornadienecyclopentadieny~h~um complexes have been studied. The decompositions of molecular ions are (i) metal-ligand bond rupture, (ii) norbornadiene skeleton destruction, (iii) substituent or hydrogen atom elimination from the norbornadiene moiety an
The following monocyclic and bicyclic 14-membered diynes all cases we obtained an intramolecular cyclobutadiene complex stabilized with a CpCo fragment (15-26). For 3 we were treated with [CpCo(cod)]: 1-oxacyclotetradeca-4,11diyne (2), 1,8-dioxacyclotetradeca-4,11-diyne (3), cyclotetra-could isolate