Manganese /
Synthesis and Magnetic Properties of Bis(Hexafluoroacetylacetonato)Copper(II) Complex with 5-Bromo-1,3-Phenylenebis(N-tert-Butylaminoxyl) as a Bridging Ligand
โ Scribed by Iwahori, Fumiyasu; Inoue, Katsuya; Iwamura, Hiizu
- Book ID
- 111909294
- Publisher
- Taylor and Francis Group
- Year
- 1999
- Tongue
- English
- Weight
- 274 KB
- Volume
- 334
- Category
- Article
- ISSN
- 1058-725X
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## Abstract The dinuclear copper(II) complexes {[Cu~2~(1,3โtpbd)(H~2~O)(OAc)~2~](ClO~4~)~2~}~0.23~{[Cu~2~(1,3โtpbd)(H~2~O)~2~(OAc)](ClO~4~)~3~}~0.77~ยท0.77H~2~O (1), [Cu~2~(1,3โtpbd)(H~2~O)~2~(OAc)~2~](ClO~4~)~2~ยท2H~2~O (2), and the tetranuclear copper(II) complex [Cu~4~(1,3โtpbd)~2~(H~2~O)~2~(SO~4~
A dinuclear Cu II complex [Cu 2 (bpp) 2 (H 2 O) 2 ](ClO 4 ) 2 (1) with 3,5-bis(2-pyridyl)pyrazole (Hbpp), has been synthesized and characterized by elemental analyses, thermal analysis, conductance, UV-vis and IR spectra. The crystal structure of 1, determined by X-ray diffraction technique, reveals