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Synthesis and isolation of stable thiirenium salts

✍ Scribed by G. Capozzi; V. Lucchini; G. Modena; P. Scrimin

Book ID
104243904
Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
135 KB
Volume
18
Category
Article
ISSN
0040-4039

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THE synthesis of a number of carbon free radicals possessing extraordinarily high inertness has been announced recently,i a most remarkable example being the perchlorotriphenylmethyl (PTM) radical (I). Such unusual behavior is ascribed to essentially complete steric shielding of the normally reactiv